1. [20pts] Consider the triose phosphate analogs shown below. O O O HO OPO3 HO F F OPO3 HO F 1 2 3 A) For each of the above molecules, identify whether or not it is a substrate for TIM. If it is a substrate, draw the final product (no mechanism is needed). If it is not a substrate, state briefly why not. (6pts) Molecule 1 TIM normally abstracts the pro-R hydrogen from triose phosphate. Since it has been replace by a fluorine which cannot be abstracted, this molecule is not a substrate for TIM. Molecule 2 This molecule is a substrate for TIM. HO H O OPO 2- F

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